State-of-the-art all-silicon sub-bandgap photodetectors at telecom and datacom wavelengths

Silicon-based technologies provide an ideal platform for the monolithic integration of photonics and microelectronics. In this context, a variety of passive and active silicon photonic devices have been developed to operate at telecom and datacom wavelengths, at which silicon has minimal optical absorption - due to its bandgap of 1.12 eV. Although in principle this transparency window limits the use of silicon for optical detection at wavelengths above 1.1 μm, in recent years tremendous advances have been made in the field of all-silicon sub-bandgap photodetectors at telecom and datacom wavelengths. By taking advantage of emerging materials and novel structures, these devices are becoming competitive with the more well-established technologies, and are opening new and intriguing perspectives. In this paper, a review of the state-of-the-art is presented. Devices based on defect-mediated absorption, two-photon absorption and the internal photoemission effect are reported, their working principles are elucidated and their performance discussed and compared

AFM imaging and plasmonic detection of organic thin-films deposited on nanoantenna arrays

In this study, atomic force microscopy (AFM) imaging has been used to reveal the preferential deposition of organic thin-films on patterned nanoantenna array surfaces - identifying the localised formation of both monolayer and multilayer films of octadecanethiol (ODT) molecules, depending on the concentration of the solutions used. Reliable identification of this selective deposition process has been demonstrated for the first time, to our knowledge. Organic thin-films, in particular films of ODT molecules, were deposited on plasmonic resonator surfaces through a chemi-sorption process - using different solution concentrations and immersion times. The nanoantennas based on gold asymmetric-split ring resonator (A-SRR) geometries were fabricated on zinc selenide (ZnSe) substrates using electron-beam lithography and the lift-off technique. Use of the plasmonic resonant-coupling technique has enabled the detection of ODT molecules deposited from a dilute, micromolar (1 M) solution concentration - with attomole sensitivity of deposited material per A-SRR – a value that is three orders of magnitude lower in concentration than previously reported. Additionally, on resonance, the amplitude of the molecular vibrational resonance peaks is typically an order of magnitude larger than that for the non-resonant coupling. Fourier-transform infrared (FTIR) spectroscopy shows molecule specific spectral responses – with magnitudes corresponding to the different film thicknesses deposited on the resonator surfaces. The experimental results are supported by numerical simulation

Deposition of Organic Molecules on Gold Nanoantennas for Sensing

The deposition of organic molecules on gold nanoantennas is reported through chemisorption for sensing in the midinfrared (mid-IR) spectral range. The specific nanostructures are gold asymmetric-split ring resonators (A-SRRs) based on circular-geometry with two different ‘arc’ lengths. The plasmonic resonant coupling technique was used to match the vibrational responses of the targeted molecules for their enhanced detection. Gold nanostructures are functionalised through chemisorption of octadecanethiol (ODT) in ethanol solution. The molecular vibrational responses were measured using a microscope coupled Fourier Transform Infrared (FTIR) spectroscopy. The experimental findings are closely supported using FDTD simulation. The modified nanoantennas surfaces are capable of supporting wide range of organic-sensing applications

Modelling of Photonic Crystal (PhC) Cavities: Theory and Applications

In recent years, many researchers have shown their interest in producing a compact high-performance optical chip that is useful for most telecommunication applications. One of the solutions is by realising photonic crystal (PhC) structures that exhibit high-quality factors in a small mode volume, V. Silicon on insulator (SOI) is one of the main contenders due to its high-index contrast between the silicon (Si) core waveguide with silica (SiO2) cladding surrounding it. The maturity of silicon photonic can also be incorporated with CMOS chips making it a desired material. A strong optical confinement provided by PhC structures makes it possible to realise the compact device on a single chip. In this chapter, we will discuss a fundamental background of photonic crystal cavities mainly on one-dimensional (1D) structures, which are the simplest as compared to their counterparts, 2D and 3D PhC device structures. We have modelled a photonic crystal cavity using finite-difference time-domain (FDTD) approach. This approach uses time-dependent Maxwell equation to cover wide frequency range in a single simulation. The results are then compared with the actual measured results showing a significant agreement between them. The design will be used as basic building block for designing a more complex PhC structures that exhibit high-quality factors for applications such as filtering, DWDM and sensors

Photonic microstructures as laser mirrors

Deeply etched 1-D third-order Bragg reflectors have been used as mirrors for broad-area semiconductor lasers operating at 975-nm wavelength. From a threshold and efficiency analysis, we determine the mirror reflectivity to be approximately 95%. The design of the GaAs-based laser structure features three InGaAs quantum wells placed close (0.5 μm) to the surface in order to reduce the required etch depth and facilitate high-quality etching. Despite the shallow design and the proximity of the guided mode to the metal contact, the threshold current density (J_(th) = 220 A/cm^2 for infinite cavity length) and internal loss (α_i = 9±1 cm^(−1)) are very low

Dual polarization operation of nanostructure arrays in the MIR region

In this paper, we report on arrays of asymmetric split H-shape nanostructures tuned to produce two distinct resonances at wavelengths that range from 3 μm to 7 μm. The electric-field of the incident wave has been both polarized parallel to the vertical asymmetric dipole arms and polarized across the 50 nm gap in the asymmetric horizontal bar. We have produced resonance quality factors as large as 26 in the mid-infrared region

Negative index fishnet with nanopillars formed by direct nano-imprint lithography

In this paper we demonstrate the ability to fabricate fishnets by nanoimprinting directly into a pre-deposited three layer metal–dielectric–metal stack, enabling us to pattern large areas in two minutes. We have designed and fabricated two different fishnet structures of varying dimensions using this method and measured their resonant wavelengths in the near-infrared at 1.45 μm and 1.88 μm. An important by-product of directly imprinting into the metal–dielectric stack, without separation from the substrate, is the formation of rectangular nanopillars that sit within the rectangular apertures between the fishnet slabs. Simulations complement our measurements and suggest a negative refractive index real part with a magnitude of 1.6. Further simulations suggest that if the fishnet were to be detached from the supporting substrate a refractive index real part of 5 and FOM of 2.74 could be obtained

Photonic crystals for light-emitting devices

Photonic crystals or photonic bandgap (PBG) structures promise to revolutionize optoelectronics by making anew class of highly efficient, low noise light emitters possible. We present data to show that their properties, in particular 2D systems, have now been fully characterized in the relevant semiconductor material system and at near-IR wavelengths, so effort can be redirected towards making active light emitters. As a first example, we present a semiconductor laser with one output mirror designed according to PBG principles. From threshold and efficiency data, we derive a reflectivity of 95 +/- 10 percent for this mirror, which underlines the viability of the PBG approach for practical devices. In order to realize the full potential of photonic crystal light emitters, however, important material issues need to be considered. Non- radiative recombination, for example, is a big problem when the photonic crystal is an integral part of the active region because of the relatively large areas of exposed surface. Several possible solutions to this problem are presented

Mapping the sensitivity of split ring resonators using a localized analyte

Split ring resonator (SRR) based metamaterials have frequently been demonstrated for use as optical sensors of organic materials. This is made possible by matching the wavelength of the SRR plasmonic resonance with a molecular resonance of a specific analyte, which is usually placed on top of the metal structure. However, systematic studies of SRRs that identify the regions that exhibit a high electric field strength are commonly performed using simulations. In this paper we demonstrate that areas of high electric field strength, termed “hot-spots,” can be found by localizing a small quantity of organic analyte at various positions on or near the structure. Furthermore, the sensitivity of the SRR to the localized analyte can be quantified to determine, experimentally, suitable regions for optical sensing